Van Dyke - Introduction, History, and Resources
Introduction/History:
The name van dyke came from the similar brown color pigment used by a Flemish painter named Van Dyck. In 1842, a man named John Herschel invented the van dyke brown process and basically, a van dyke process uses silver and iron to make it photo-sensitive. Arndt and Troost developed this process in 1895 after John Herschell. It produces nice brown tone prints.
John Herschel, 1867, by Julia Margaret Cameron - from wikipedia
From what I understand, the van dyke process is similar to callitype and the alternative names are brown prints or sepia prints. This not to be confused with any other photogenic process such as callitype or talbotype. The procedure may be similar, but it is not the same. It can even be applied on different materials other than paper like wood or fabric, as long as there is appropriate coating for it to be absorbed on.
Most of the recipes were similar though, just a few modifications in between. Arndt and Troost had their own formulas that is similar to what we use now, however, there are some differences. Arndt and Troost's formula for the van dyke process consisted of 80-100 grams of ammonio-citrate iron, 12-20 grams of silver nitrate, 15-20 grams of tartaric acid, 10-15 grams of gelatin, and 1 L water
Even now, some people developed their own recipes or follows someone else's recipes that is not exactly the same. We may have something that looks like this now:
Solution A: 35 mL distilled water and 10 grams iron ammonium citrate.
Solution B: 35 mL distilled water and 1.5 grams tartaric acid.
Solution C: 35 mL distilled water and 4 grams silver nitrate.
Mix solution A and B. Then mix it with solution C. It is applied on a piece of paper and one need to make sure that it is uniform, because you have both the silver and iron - it will just looks messed up if it's not done the right way. Negatives are used for this process. After the exposure, it is washed out. Citric acid is used in this process because of the acid level - it helps wash out the ferrous salts. After this, the hypo solution was used. Then it needs to be washed out under fresh running water. (The professor said that it's really just for archival purposes - if you want the prints to last forever, then this step is necessary to remove all of the remaining chemicals.)
Another thing that I noticed that we did not conduct in our lab was the toning process. From what I found, there are three different kind of toners which are palladium, gold, and platinum.
The recipe for palladium may look like this: 20 mL 20% palladium, 5 grams citric acid, and 1,000 mL distilled water. The recipe for gold toner consists of 5 mL 5% gold chloride, 5 grams citric acid, and 1,000 mL distilled water. Platinum toner may consists of 20 mL 20% platinum, 5 grams citric acid, and 1,000 mL distilled water. By using different toners, it produce different color results. Some people may modify their recipes or follow someone else's for the toning process as well. I think it does not really matter, what's more important is to tone the print if you plan to keep it for a long time.
In addition, I also noticed more than one article talked about how the van dyke prints do not last and how some people did not like the van dyke process because of this. Several authors explained that if it was not done properly, then the print will fade and become no good. So to keep the prints, one need to really process it by making sure that the iron is removed, fix the image, and wash it out really good. The last and important step is the toning. Other processes require the images to be toned in order to make it last as well and the van dyke process is no exception.
Examples of some Van Dyke prints:
Voigtlander pinhole, Van Dyke brown print
Broken pomegranates by Wynn White, van dyke process
The information above does not belong to me and comes from these resources.
http://www.alternativephotography.com/wp/processes/kallitypes/vandyke-notes
http://www2.ntm.cz/projekty/fototechniky/en/index.php?text=six
http://www.shadesandcolors.com/vdarticle.html
Buffaloe, Ed. "Ferric-Silver Formulae." Unblinking Eye - Photography, Darkroom, Alternative Process, Historic Photographic Processes, Travel. Web. 08 May 2011. <http://unblinkingeye.com/Articles/Ferric/ferric.html>. * (Lots of excellent information.)
http://www.webexhibits.org/pigments/indiv/overview/vandyke.html