#nanocrystal

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File:Macroscopic picture of a film of cellulose nanocrystal suspension cast on a Petri dish (diameter 3.5cm)..jpg

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Quantum Dot Solids For Next Gen Computing and Electronics

Quantum Dot Solids Breakthrough: Managed Charge Dynamics Enables Advancements in Electronics The Nanocrystal Charge Transport Challenge

Researchers are still studying quantum dots (QDs)-based “designer solids” with potentially revolutionary computing and electronics applications. Electrical applications have lagged behind quantum dot solids, which have made commercial success by powering bioimaging, LED displays, and lighting with their tunable optical capabilities. Solar cells, photodetectors, transistors, spintronics, and solid-state quantum simulators for quantum computing have yet to advance. The inability to modify electrical characteristics and the ambiguity of charge transport systems are the key reasons for this stagnation.

Electric conductivity has long been a problem with nanocrystal quantum dot materials. Because disorder and localized states, or “traps,” affect charge transport in these materials, Ohm's Law and the Drude model are often insufficient. Abnormal transport behavior includes non-linear current-voltage correlations and diffusion aberrations.

Nano-Patterning Separates Conductance Channels

Tamar S. Mentzel, Sk Tahmid Shahriar, Xiangxi Yin, Bence Papp, and Shane Revel from the University of California, Riverside discovered a way to simplify these complex dynamics. The team invented nano-patterning to make highly organized quantum dot solids. This precise manufacture minimized structural faults including cracking, clustering, and grain boundaries, allowing researchers to discern charge channel behavior. A 70-nanometer-wide material without structural faults was created by researchers. It was possible to isolate and precisely quantify charge dynamics in a single conductance channel in a percolation network. Conduction Noise Drives Nanocrystal Transport A surprise result of extensive tests on this highly ordered material was conductance noise levels that approached 100% of the average current. This showed charge flow irregularities. Time-resolved experiments showed that conductance noise changes the channel's ability to conduct electricity, so the current fluctuated linearly with the standard deviation. Average current and noise increased exponentially with applied voltage. Charge tunneling via surface ligand potential barriers matches this behavior. Analyzing the noise spectrum revealed a power law dependence, ruling out pink or white noise. Modeling the material as a percolation network, the study suggested that charge transport largely occurs by hole carrier tunneling between nanocrystals. The lowest-resistance channels drive this network's current. Importantly, trap states inside these main pathways affected conductance significantly. Additional time-dependent current measurements discovered a random telegraph signal (RTS), indicating that surrounding trap states were forcing a single conductance channel to switch on and off. Histograms of off-times show a power law with a long tail for trap depths and trapping times.

Lévy Statistics and Phonon-Assisted Tunneling Modeling Disorder

QDs were tested that were colloidal lead sulphide (PbS). Researchers found that chaos in the energy environment, including nanocrystal size and spacing, generated hopping rate oscillations. Lévy statistics could explain the extraordinarily variable and aberrant transport behavior, according to the researchers. Lévy statistics, which represent random events with high volatility, show charge carriers bounce between localized states. Analysis of long-time dynamics revealed a Lévy distribution during intermediate periods. The researchers described charge transport using a stochastic model based on quasi-one-dimensional percolation channels. They observed that charge trapping events dynamically affect nanocrystal transport by modifying phonon-assisted tunneling. QD arrays' transport properties are similar to those of other disordered systems like glassy materials and amorphous semiconductors, however this stochastic model was able to prove the ergodic hypothesis and describe the system as stationary. Future Directions: Passivation/Defect Reduction Results show that defects and trap states are important and that researchers must modulate their density to improve charge transmission. The work emphasises surface chemistry and passivation of QDs to minimise surface defects and control trap state density. This approach allows the logical design of nanocrystal solids with certain electrical properties. While admitting residual disorder caused by site energy and tunneling coupling, the researchers recommend improving electrical control by stronger passivation and nanocrystal coupling. Future research will explore QD materials and architectures, develop new passivation procedures to reduce trap density, and use more complicated models to understand transport phenomena. Optimizing solar cells and photodetectors employing these materials for cutting-edge optoelectronic devices requires this expertise.

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Nanocrystal links could lead to better electronics

Nanocrystal links could lead to better electronics

Chemists and engineers today are very interested in a kind of nanotechnology enabled by tiny islands of nanoparticles called “colloidal nanocrystals.” They can be made out of abundant and non-toxic materials, and they can be easily tweaked to have a number of different properties as a function of their size. Depending on how they’re built, colloidal nanocrystals could be made into solar panels,…

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“rotating nanocrystal”

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Samsung reveals nanocrystal SUHD TVs, a new SSD, and more at CES 2015

Samsung reveals nanocrystal SUHD TVs, a new SSD, and more at CES 2015

Samsung reveals nanocrystal SUHD TVs, a new SSD, and more at CES 2015 At this year's CES 2015, Samsung went beyond OLED TVs and introduced nine different models of SUHD TVs for the coming year that all incorporate nanocrystals to enhance the LCD backlights, resulting in brighter images with a wider color gamut than the … Read more on CNET

Samsung Electronics to Launch Tizen TVs In February LAS…

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[randdmag]

Luminescent nanocrystal tags, high-speed scanner enable rapid detection of pathogens

A research team using tunable luminescent nanocrystals as tags to advance medical and security imaging have successfully applied them to high-speed scanning technology and detected multiple viruses within minutes. The research builds on the team's earlier success in developing a way to control the length of time light from a luminescent nanocrystal lingers. 

Read More - http://www.rdmag.com/news/2014/05/luminescent-nanocrystal-tags-high-speed-scanner-enable-rapid-detection-pathogens