Prussian Blue finally transformed into octahedral structure after 300 years
For the first time in more than three centuries, Prussian Blue—long confined to its rigid cubic shape—has been transformed into an octahedral structure. A research team has successfully synthesized this new morphology by replacing water with a specialized solvent, glycerol, during the crystal growth process. Their findings were recently published online in Advanced Functional Materials. Accidentally discovered around the 1700s, Prussian Blue possesses a hollow three-dimensional framework that allows ions to move in and out with ease. These unique properties have enabled its use across diverse fields, from sodium-ion battery electrodes to radioactive cesium removal, catalysis, and environmental remediation. However, until now, its morphology had been limited. When synthesized in water, the reaction proceeds too quickly, making it difficult to control particle growth and producing only cubic particles. This constraint has prevented scientists from exploring shape-dependent properties or unlocking new applications.
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