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Mood Headcanon
Orihime’s mood can change quite quickly depending on the situation(s) she’s put in. Most of the time, she is happy, and cheery. The kind of out-going, happy-go-lucky type of person. She believes in staying positive, and doing good no matter what.
Anger Headcanon
When Orihime becomes angry, it’s almost as if you’re seeing an entirely different person, because her face simply isn’t the type of face to frown. It can be a little scary sometimes, and at that point, she’s more than determined to do the right thing if necessary—whatever that may be—even if she isn’t the strongest of people around. Making Orihime angry won’t really do you any good, but it’s not as if she’ll lash out on you either. Her beliefs are her own and she’ll stick with them to the end.
Love or Sexuality Headcanon
Orihime loves many things, some of those things being cooking/baking, her friends, family, and various other things that she may enjoy. However, when it comes to loving someone, she keeps quiet, as she has with Ichigo all these years. She’d do anything for him, because she loves him, but it’s similar with any of her friends too. She’d do anything for her friends if it meant their safety.
When it comes to her sexuality, Orihime has never thought of a girl, or being with a girl in any sort of relationship other than family or friend. It’s only ever been natural to her that a man and a woman should be together. However, sex itself is something that rarely ever comes to mind with Orihime. Someone would have to bring it up for her to think about it all actually, so you won’t catch her as the dirty-minded type at all. However, if a comment is made directly to her that is, or may seem sexually intended, it won’t take long for her mind to jump to conclusions and for her to have a little panic attack or something like freaking out.