Ceramics: Titanium carbide
A well-known material, titanium carbide is a refractory ceramic, extremely hard and capable of withstanding high temperatures, among many other advantageous properties. A binary compound, it is the only carbide in the titanium-carbon system. It’s composition is equal parts titanium and carbon by atomic percent (crystal structure shown above, with the atoms not to scale) but by weight percent the material is around 80% titanium. The crystal structure is face centered cubic, and the Mohs hardness of the material is between 9-9.5.
Titanium carbide can be synthesized in a number of ways, including the reduction of carbon black with titanium oxide, direct carbonization of titanium powder, chemical vapor deposition, the blast impact method (mixing titanium dioxide powder and carbon powder), and ball milling, among other techniques. It does occur in nature, but only rarely, in the form of the mineral khamrabaevite.
Applications of this ceramic rely mainly on the first two properties mentioned: its hardness, and its temperature resistance. Its addition to cutting tools takes advantage of the former, while its addition to crucibles takes advantage of the latter. In addition to these uses, titanium carbide is also used in cermets (composites made of ceramics and metals), as abrasion resistant coatings on tools, and as heat shield coatings in spacecraft.
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