13, 42 for Maiko?
13. Do they have potential to be toxic if they’re usually healthy?
Yeah. They definitely do.
Neither of them are incredibly good at expressing their emotions. Zuko is passionate and loud, but also very rash and temperamental, Mai is quiet and composed but that means she holds everything back until she explodes. When they fight, they fight. And it's not pretty. So I would say what toxicity their relationship does have is less like not supporting each other or being controlling or dishonest or anything like that - if these two would be toxic, it would be due to lack of communication. (Good communication, specifically - Zuko yelling and Mai not talking is not a good combo. And yeah, Zuko does, canonically, get jealous. So maybe a little of that, too.)
42. Who is the sensible mature one?
I would argue Mai, personally. I think Zuko is smart - a lot smarter than many people seem to give him credit for - but like I said above, he's a little rash and temperamental, and while he can definitely be mature and make hard decisions, he can also act purely on instinct. I think Mai is more the one who sits back, thinks about the possibilities a bit more, and makes the "mature" choice.
(Which is something, I think, that she has to un-learn to an extent as she grows up - she has to unlearn how to always be the quiet thinker, and has to learn that sometimes, it's okay to act on instinct alone.)
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