I haven't been doing much with the perytons because I'm very unsatisfied with their design, but here's something for you: the inhabitants of Within-the-Loop, the ancient megastructure they live on, have siblings!
There have been a few other planets discovered within the Milky Way Galaxy which host life-forms with markedly unusual biochemistry that all arose at around the same time (~5 billion years ago). Each uses a different solvent, and some are boron- or metal oxide-based instead of carbon-based. (No silicon-based life-forms, though.)
All of the planets hosting them orbit K-type stars, and upon closer inspection all have some sort of self-maintaining artificial structures, invariably including a supercomputer which periodically manufactures and sends out semi-autonomous bots to survey the biosphere. It seems the creators simply wanted to see how much was possible regarding synthetic life.
Perytons are the only sophonts among this collection, though. Indeed, the life of Within-the-Loop is by far the most complex — the life on most of the other planets never got past the prokaryote stage, and the second most complex biosphere after Within-the-Loop is comparable to the early Paleozoic.