A bit of an unguided ramble, but i recently began looking into sources of tannins to tan hides. I'm trying out a sort of hybrid egg tan and tannin tan where i do the emulsified fats first, then replace the smoking step with a tannin bath.
Ive tried it with a scrap of gray fox hide and oak galls, and it went pretty well. But for my newest thing I'm gonna focus on, I gathered a bunch of water oak acorns. They're of the black oak group, which means they're higher in tannins and less palatable than the white oak group. Which is good for tanning, of course!
I gathered a large jarful, crushed them up, and then boiled them. I poured the water off into a bigger pot, and then boiled them a second time in new water. I added a silver cross fox fur scrap that i had tanned using eggs, but was in need of further treatment.
The next day i added in the second boil of the acorns to get any straggling tannins into the bath, and made sure to stir it. So far so good.
However, on the third or fourth day, i went to go get it off the deck and rinse/dry it out. I reached in, and lo and behold, it was slimy! All the water was viscous, and it smelled like yeast and alcohol. I guess it had started fermenting?
I took it out, and despite being obviously slippery, it seemed intact. I hosed it off in the driveway, which took longer than the quick dip in a bucket i had planned, and everything seemed fine! The leather was brown and the fur was still intact, it just took forever to get the slime out.
I dried out the hide by leaving it in the sun in a driveway, a railing, back of a chair, and eventually hanging it on the mantle once it was mostly dry. The leather was soft, the color was even, and the fur was clean.
And just to focus on the fur, it seems so much fluffier than it was before! I don't know if i'm seeing things, but it seems to have cleaned and revitalized it, maybe because of the soak in alcohol and acorn fats?
Anyways, what i think happened is that the boiling extracted starches along with the tannins and oils, the starches broke down and got fermented by wild yeast, thus producing alcohol. The acorn oil and alcohol could've even helped clean off the fur!
Ive also heard of cold leaching acorns to extract the tannins in order to make bread with the resulting flour. Which (i hypothesize) would leave more of the starches and oils in the nut part than crushing and boiling. But the stuff i read made no distinction between hot and cold leaching in the context of tanning.
Do i know all this for sure? No, but i kinda wanna test it out at some point soon. cold leaching vs hot leaching vs straight water vs nothing. I'm also curious if anyone else has messed around with acorn tanning before. I'm pretty new to it so it'd be cool to learn more!
(it also makes the second time ive accidentally made alcohol, the first one coming from wild rice)