*biologist crashes through the underbrush*
Ok so here’s the thing though
Malachite is not poisonous to YOU. BUT fucking this stalactite will probably wreck your vaginal flora and leave you with a gruesome infection within a couple days.
Want details? SO GLAD YOU ASKED, ‘CAUSE HERE THEY ARE.
• Malachite is not copper oxide. It’s Cu2CO3(OH)2. Like most carbonates it’s water soluble– that’s how it became a stalactite in the first place! And technically any given chunk of “malachite” isn’t just malachite– it’s a mix of various copper carbonates & oxides. This will become important later.
• When malachite dissolves it makes a bunch of copper (Cu++) ions. Cu++ is GREAT at killing bacteria and fungi– so good at it that sprays with Cu++ get used a lot as a spray in agriculture to stop plant disease. It takes such a large dose to harm larger organisms that copper sprays are used a lot in organic agriculture (like Bordeaux mixture).
So bottom line, yes malachite is technically nontoxic to humans. But it kills bacteria when it dissolves and releases Cu++.
• Malachite dissolves somewhat slowly in water– but vaginal secretions aren’t just any water. A healthy human vagina has a pH of 3.8-4.5 and a salinity of about 0.9%. It’s also warmer than your average underground cave at 37°C (or 98.5°F in American meat units). As luck would have it, acidity, salinity, and warmth all make malachite dissolve faster.
• In other words, the human vagina dissolves malachite.
• I have no deeper explanation for why human females can dissolve rocks with our genitals. It simply is.
• Gonna to take a quick moment to point out that sex toys that dissolve when you use them are maybe not the best investment.
• Anyway the key question now is “how fast does the human vagina dissolve malachite?” Are we talking geological timescale, a Nazis-in-Indiana-Jones situation, or something in between? If the reaction kinetics of dissolution are very slow, then there’s nothing to worry about. An encounter with a stalactite would have to last years for enough Cu++ to leach out to cause problems. If it’s quick then we’re in trouble.
• Unfortunately it looks like nobody really knows. One of the best sources on how malachite dissolves & precipitates in water– an EPA document on how to avoid too much Cu++ in municipal drinking water systems– helpfully says “The kinetic constraints on the formation of these solids in water systems are largely unexplored” (p. 42) because end equilibrium points is all you need to run a city water system safely. In other words, the experiments that would tell us how fast malachite dissolves in various types of water just don’t exist because nobody’s ever needed to know before. So we’d better assume it’s going to happen reasonably quickly, #for safety.
• So in best scientific fashion, we’re just going to bullshit our way ahead using what facts we DO have on hand: endpoint equlibria.
• Is there any info out there telling us what equilibrium concentration of Cu++ we get in salty acidic water at body temperature? Almost! One J.F. Scaife published some great data on this back in 1957. TAKE IT AWAY, SCAIFE.
That orange box is how many moles of dissolved Cu++ Scaife got from sticking malachite in some water that had 0.171 moles NaCl/L (body salinity is about 0.154 moles NaCl/L so this is slightly less salty than people) at 30°C. He’s got no acidity in there, and again the salinity and temperature are slightly lower than people. But this is probably the closest we’re going to get to data on how malachite behaves in vaginas anytime soon, folks. From this we can take away that if you leave malachite alone in a vagina you’ll get AT LEAST 9.12 x 10^-4 moles/L, or 5.8 ppm, of Cu++ at equilibrium.
• Recall from above that most “malachite” isn’t actually pure malachite, it’s a mix of various copper carbonates & oxides. The EPA document elaborates: “[T]raditional ‘eyeball’ identification of malachite by its blue-green color is extremely unreliable, because almost all cupric hydroxysulfates, hydroxycarbonates, hydroxychlorides, and even fresh cupric hydroxide can be some shade of blue-green. … Thus, the uncertainty in the computed copper concentration in equilibrium with malachite is at least about a factor of 2 … until further experimental data focusing on this problem is generated.”
In other words, “do your math and then double how much Cu++ you think is going to be in the water, just in case.” So that gives us 11.6ppm Cu++, at equilibrium, with malachite in a (til now!) healthy vagina.
• Next step: do we have any idea what happens to bacteria in acid conditions with copper? OH MY GOD WE TOTALLY DO. Gyawali et al 2011 checked this out in the context of “so what if we rinsed tomatoes with a solution of lactic acid and copper, because that would be a safe & organic way to get rid of E. coli?” So now this post has officially ruined stalactites, vaginas, and tomatoes.
^This would happen. These are the counts of 4 E. coli strains exposed to various levels of lactic acid & Cu++ for 8 hours. This table only shows the end counts but it represents the death of 99.7% of bacteria*.
• Losing 99.7% of your vaginal flora is seriously bad news. You’re looking at really good odds of a yeast infection, bacterial vaginosis, and/or other infection issues. And that’s if you’re lucky enough to not be in the 4% of the population or so that’s sensitive to skin contact with copper.
• The good news? Biochemically speaking, you’re probably ok to put it in your butt. It’s not as acidic or salty in there, plus there’s a huuuuuge stockpile of gut microbes right upstream that can quickly repopulate the colon after spelunking is complete. However this stalactite is not flared at the base so it is the wrong shape for putting in your butt. Do not put this stalactite in your butt.
• This all looks like fun and games, but I think it’s really interesting that the internet’s mistake in concluding that this stalactite is fuckable is very similar to the mistake made by the Flint water management system. Hear me out.
• Central to the Flint lead poisoning crisis is that authorities only looked at & tested Flint’s water in its central treatment plant before it went out through the pipes. Not after it went through the pipes. They did not consider what would happen biochemically as it went through the pipes and metals started dissolving.
• Similarly, in concluding that the stalactite is fuckable, the internet only considered the stalactite itself. Not the biochemical processes that would happen to it as it, welp, went through the pipes.
• Media frequently reports that the Flint River’s water is “corrosive,” leading many to believe the river is full of industrial waste. This ain’t the case. You’d need industry to fill a river with industrial waste, and industry left decades ago. That’s why Flint’s so poor. So what IS in the water? Road salt. Plain old stupid road salt. The old Detroit-based source didn’t have salt because it came from Lake Huron which has a large, mostly rural watershed. Meanwhile the Flint River runs through a lot of towns, making it slightly salty as everything melts down in spring. And as we recall from the stalactite experience, a little salt is all it takes to get metals to dissolve.
• Information on this engineering problem was not coming through clearly from the engineering or chemistry sides. It took a biologist, pediatrician Mona Hanna-Attisha, to document the real-time results and provide the data to kick-start a high-level investigation.
• Morals of the story: when dealing with a biological system pls consider asking a biologist, your vagina and/or city could depend on this
• Pls use a condom when fucking any water-soluble material
• Still don’t put the stalactite in your butt -3/10 do not recommend
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